Roast bell peppers until the skin blisters and darkens, cover them briefly so trapped steam loosens the skin, then peel when cool enough to handle. The flesh should become tender, but it need not turn to mush. A broiler or a hot oven can do the job; the best choice depends on how closely you can watch the peppers.

Prepare broad pieces for even exposure
Choose firm bell peppers without mold or leaking soft spots. Red, yellow and orange peppers tend to taste sweeter than green ones. Wash and dry them, then cut around the stem and remove the seeds and pale ribs. Cut into broad panels or halves that can sit with their skins facing upward.
Flatten curved pieces gently so more of the skin is exposed to the heat. A small curve is fine, but tall domed pieces can blacken on top while their lower edges remain stubbornly unblistered. Whole peppers can also be roasted, though they require turning and are messier to seed afterward.

Use the broiler with close attention
Arrange pepper pieces skin-side up on a sturdy rimmed metal tray approved for the broiler. Do not use parchment close to a broiler element. Position the rack according to your appliance instructions and start farther from the heat if uncertain.
Broil until the skin blisters and develops broad dark patches, checking frequently and rotating the tray if one side cooks faster. This often takes several minutes, but broilers vary too much for a fixed time to be reliable. Stay nearby. The goal is darkened skin over tender flesh, not flames or deeply burnt flesh.
Move finished pieces to a heatproof bowl as they are ready rather than forcing every pepper to wait for the slowest one. If edges are charring while large areas remain raw, increase the distance from the heat and turn the tray.
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Choose an oven when gentler cooking suits the meal
A hot oven around 425°F/220°C gives more gradual cooking than a broiler. Spread the prepared peppers on a rimmed tray and roast until softened and blistered, checking from about 20 minutes onward. Thickness, water content and tray loading change the time. This approach is useful when you are roasting other vegetables, although the skins may not slip off as completely as after strong blistering.
A little oil can help roasting and seasoning, but it is not essential for a skin-removal method. Keep any oil layer thin. Oil pooled on a hot tray can smoke, and too much fat makes the finished peppers slippery to handle.

Cover, cool and peel
Cover the bowl with a plate for roughly 10–15 minutes, or until the peppers are comfortable to touch. Trapped steam helps separate skin from flesh. Open away from your face because hot vapor can escape. There is no need to seal very hot peppers in a thin plastic bag.
Pull the loosened skin away with your fingers or a small knife. Remove obvious charred patches but do not tear away large amounts of good flesh to chase every tiny speck. If a patch refuses to peel, it probably did not blister sufficiently. Next time, adjust the piece’s position or give that section more direct heat.
Avoid rinsing peeled peppers under the tap unless necessary to remove unwanted debris. Rinsing carries away some flavorful juices. Instead, scrape off stray seeds and skin with the knife or wipe lightly with a clean damp towel.
Season and store as a cooked vegetable
Slice or tear the peeled flesh and season with a little olive oil, salt and an acidic ingredient to taste. Add to sandwiches, grain bowls, pasta or a blended sauce. Taste before adding sweetness: ripe roasted peppers may already be sweet enough.
Refrigerate promptly in a clean covered container and use within the usual 3–4 day window for cooked leftovers. For longer storage, freeze portions. Oil poured over peppers does not make them shelf-stable, and a splash of vinegar is not a tested preservation formula.
If you want jarred peppers that can safely sit in the pantry, use a current tested canning or pickling recipe with its exact preparation and processing instructions. Roasting, peeling and covering with oil are culinary steps, not substitutes for those safety controls. Keep the everyday batch small enough to enjoy while its flavor and texture are at their best.
Related kitchen guides
Continue with How to Make Stuffed Peppers With Tender Shells.
Continue with How to Make Ratatouille With Distinct, Tender Vegetables.
Sources and further reading
extension.oregonstate.edu: Roasted Bell Peppers
extension.oregonstate.edu: Sp 50 454 Preserving Peppers
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